Generally it was answered in comment, however I'll add references from official kubernetes documentation.

env field uses EnvVar array. Based on EnvVar v1 core API group, name and value should be only strings. Please see EnvVar v1 core

And here is an official example to see how variables are set:

apiVersion: v1
kind: Pod
metadata:
  name: dependent-envars-demo
spec:
  containers:
    - name: dependent-envars-demo
      args:
        - while true; do echo -en '\n'; printf UNCHANGED_REFERENCE=$UNCHANGED_REFERENCE'\n'; printf SERVICE_ADDRESS=$SERVICE_ADDRESS'\n';printf ESCAPED_REFERENCE=$ESCAPED_REFERENCE'\n'; sleep 30; done;
      command:
        - sh
        - -c
      image: busybox
      env:
        - name: SERVICE_PORT
          value: "80"
        - name: SERVICE_IP
          value: "172.17.0.1"
        - name: UNCHANGED_REFERENCE
          value: "$(PROTOCOL)://$(SERVICE_IP):$(SERVICE_PORT)"
        - name: PROTOCOL
          value: "https"
        - name: SERVICE_ADDRESS
          value: "$(PROTOCOL)://$(SERVICE_IP):$(SERVICE_PORT)"
        - name: ESCAPED_REFERENCE
          value: "$(PROTOCOL)://$(SERVICE_IP):$(SERVICE_PORT)"

Link to this example is here